It does take a bit getting used to. My first dive in a pool was disaster. By the time I moved on to open water, even then the first few were a bit unstable.
Having a properly fitting harness is one of the biggest things. If it's too loose, then your backplate tends to "rock" and you'll end up wanting to turn turtle and roll on your back.
Proper trim is another issue. If the tanks are too low, it tends to pull you down. This can sometimes be solved by moving the bands, the backplate, or the wing to adjust trim out.
I set my gear in a pool and adjusted it til it would float almost horizontal on its own and used that for a base point for making adjustments while I was diving it.
Once you get used to doubles, you will love the stability vs. single tanks.
Good luck!