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  • Gas analysis - Keeping yourself safe while diving

    Recently I read a harrowing article about two divers who almost died and are suffering long term debilitating effects from breathing what we generally refer to as “Bad Gas”. The impetus of this article is to help readers know what “Bad Gas” is and some tips as to how to avoid getting & breathing “Bad Gas”.

    Florida law requires any vendor of breathing gas to have it tested on a quarterly basis at a minimum. Industry standards require vendors have it tested anytime they suspect that some event has made the potential for them to be pumping “Bad Gas”. The vendor should post the gas analysis certificate in a conspicuous place for customers to view. Some vendors only post the certificate, some post the actual test results similar to what is shown below. Clearly you should make sure you see these certificates and read them. While it is no guarantee the gas is good, it is a good start.

    What is “Bad Gas”? There are standards for purification that determine whether or not a gas sample meets minimum standards for purity. There are several things that are checked in order to help make this determination. Some of the more obvious ones are: Carbon Dioxide, nitrogen, oxygen, argon, carbon monoxide, water vapor, hydrocarbons, methane, and oil.

    Some of the things you can also do is to take a look at the compressors where you get your gas fills. If they are dirty that should tell you something. Dirty compressors do not cool as well as clean compressors. The very fact that a compressor is dirty tells me volumes about the staff at the facility. Consider the ventilation around the compressor. Compressors need to be cooled – many operators blow air across the compressor while it is running.

    If the air temperature around the compressor is hot it can render the Hopcalite in the filter to be ineffective. Hopcalite is a catalyst that coverts carbon monoxide to carbon dioxide. If the Hopcalite gets much above 100 degrees Fahrenheit it will no longer convert CO to CO2. Hopcalite is advertised to handle as high as 300 ppmv of CO. If the oil reaches its flashpoint the Hopcalite will be unable to handle & convert that volume of CO to CO2 so you will get a lot of CO in the breathing gas.

    If the gas coming through the filter is moist it will also render the Hopcalite ineffective. The dew point must be at least -50 degrees Fahrenheit. Because of this there must be a drying agent in the filter before the gas reaches the Hopcalite in the filter. You can note that the CO in the reported sample is less than 0.3 ppmv. The filter in this compressor has a Hopcalite layer in it.

    Compressor operators are wise to run their compressors when it is cool and dry, if at all possible. Running the compressor at the hottest and most humid part of the day may be required to meet gas volume demands. If the compressor is being run during these times extra care should be given to cooling the compressor and ensuring adequate ventilation.
    Compressor operators should be using synthetic oil rather than mineral oil. Synthetic oils have a higher flashpoint, are not as bad for you if breathed. (But it is still not good). Ask your vendor what they use; you may be surprised at some of the responses.

    Operators would also be wise to install CO monitors in their gas system. CO monitors are available for purchase at retail for $400. This seems to me a small price to pay for the vendor to constantly monitor for CO. These are also relatively simple to install. Ask your vendor if they have a CO monitor.

    After you get your tanks filled and before you connect your regulator to your tanks crack open the valve and perform a ‘sniff test”. While this test is not all encompassing it may yield a result that will tell you NOT to dive that gas. If the gas has any odor to it at all, do not breathe it. Tell the supplier of that gas that it has an odor and give them the opportunity to correct any problem that may exist. Some people I know have sent samples of these bad smelling gasses out for analysis.
    Comments 15 Comments
    1. Capt Jim Wyatt's Avatar
      Capt Jim Wyatt -
      Thanks to Capt Frank Wasson who correctly pointed out that it is no longer a Florida law for facilities to have their gas tested. Of course it is still an industry standard.

      Jim
    1. gsxr1997's Avatar
      gsxr1997 -
      Quote Originally Posted by Capt Jim Wyatt View Post
      Thanks to Capt Frank Wasson who correctly pointed out that it is no longer a Florida law for facilities to have their gas tested. Of course it is still an industry standard.

      Jim
      Statutes & Constitution :View Statutes : Online Sunshine



      really? i think Capt Frank is misinformed
    1. gsxr1997's Avatar
      gsxr1997 -
      effective july 2012
    1. gsxr1997's Avatar
      gsxr1997 -
      Florida has repealed their statutes EFFECTIVE JULY 2012 ,though that does not eliminate OSHA standards which require that air tests be performed semi-annually


      TITLE 29--LABOR

      CHAPTER XVII--OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT
      OF LABOR

      PART 1910--OCCUPATIONAL SAFETY AND HEALTH STANDARDS--Table of Contents

      Subpart T--Commercial Diving Operations

      Sec. 1910.430 Equipment.

      (a) General. (1) All employers shall comply with the following
      requirements, unless otherwise specified.
      (2) Each equipment modification, repair, test, calibration or
      maintenance service shall be recorded by means of a tagging or logging
      system, and include the date and nature of work performed, and the name
      or initials of the person performing the work.
      (b) Air compressor system. (1) Compressors used to supply air to the
      diver shall be equipped with a volume tank with a check valve on the
      inlet side, a pressure gauge, a relief valve, and a drain valve.
      (2) Air compressor intakes shall be located away from areas
      containing exhaust or other contaminants.
      (3) Respirable air supplied to a diver shall not contain:
      (i) A level of carbon monoxide (CO) greater than 20 p/m;
      (ii) A level of carbon dioxide (CO2) greater than 1,000
      p/m;
      (iii) A level of oil mist greater than 5 milligrams per cubic meter;
      or
      (iv) A noxious or pronounced odor.
      (4) The output of air compressor systems shall be tested for air
      purity every 6 months by means of samples taken at the connection to the
      distribution system, except that non-oil lubricated compressors need not
      be tested for oil mist.
    1. gsxr1997's Avatar
      gsxr1997 -
      Quote Originally Posted by gsxr1997 View Post
      Statutes & Constitution :View Statutes : Online Sunshine



      really? i think Capt Frank is misinformed
      Florida Statute will be repealed effective July 2012 , this will not mean that shops do not have to comply with OSHA Standards as follows:
      TITLE 29--LABOR

      CHAPTER XVII--OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT
      OF LABOR

      PART 1910--OCCUPATIONAL SAFETY AND HEALTH STANDARDS--Table of Contents

      Subpart T--Commercial Diving Operations

      Sec. 1910.430 Equipment.

      (a) General. (1) All employers shall comply with the following
      requirements, unless otherwise specified.
      (2) Each equipment modification, repair, test, calibration or
      maintenance service shall be recorded by means of a tagging or logging
      system, and include the date and nature of work performed, and the name
      or initials of the person performing the work.
      (b) Air compressor system. (1) Compressors used to supply air to the
      diver shall be equipped with a volume tank with a check valve on the
      inlet side, a pressure gauge, a relief valve, and a drain valve.
      (2) Air compressor intakes shall be located away from areas
      containing exhaust or other contaminants.
      (3) Respirable air supplied to a diver shall not contain:
      (i) A level of carbon monoxide (CO) greater than 20 p/m;
      (ii) A level of carbon dioxide (CO2) greater than 1,000
      p/m;
      (iii) A level of oil mist greater than 5 milligrams per cubic meter;
      or
      (iv) A noxious or pronounced odor.
      (4) The output of air compressor systems shall be tested for air
      purity every 6 months by means of samples taken at the connection to the
      distribution system, except that non-oil lubricated compressors need not
      be tested for oil mist.


      if this reposts ,I apologize in advance as it is not showing up in my browser for some reason
    1. gsxr1997's Avatar
      gsxr1997 -
      Quote Originally Posted by gsxr1997 View Post
      effective july 2012
      IF it passes!
    1. Travis B's Avatar
      Travis B -
      yikes
    1. Superlyte27's Avatar
      Superlyte27 -
      it already passed.
    1. davetowz's Avatar
      davetowz -
      I am probably wrong, but I think the 29 CFR entry that you are posting applies to commercial diving, not the recreational dive world.
    1. gsxr1997's Avatar
      gsxr1997 -
      Quote Originally Posted by davetowz View Post
      I am probably wrong, but I think the 29 CFR entry that you are posting applies to commercial diving, not the recreational dive world.
      if you receive any renumeration for the air then OSHA regulations apply
    1. gsxr1997's Avatar
      gsxr1997 -
      Quote Originally Posted by Superlyte27 View Post
      it already passed.
      actually , it has not . it passed a subcommittee vote and is in health and human services committee now- if they pass it ,it will then go to a vote on the floor of the house and senate - only then will it have passed
      House Bill 4037 (2012) - The Florida Senate
    1. theduckguru's Avatar
      theduckguru -
      I can understand both the pros and cons of Florida HB4037, but I find it really interesting that some of the LDS owners who are spouting "its life support equipment" to the students may be telling his elected officials that air testing is an unneeded burden.
    1. mdax's Avatar
      mdax -
      If you really want to cause a stir post that shops should keep testing their gas, post results online and install CO monitors...not only do shops not care but many of your fellow divers believe these steps are unimportant.
    1. theduckguru's Avatar
      theduckguru -
      Quote Originally Posted by mdax View Post
      If you really want to cause a stir post that shops should keep testing their gas, post results online and install CO monitors...not only do shops not care but many of your fellow divers believe these steps are unimportant.
      If society desires a more fair and effective regulation, the testing period would be based on hours of compressor operation rather than the position of the moon.
    1. dsdiving's Avatar
      dsdiving -
      I get my fills from a buddy who runs a Commercial outfit. Not that I don't want to support my LDS but I've have too many issues over the years with fills. My Buddy relies on his air for his crew and operations. Even if he didn't have to have it tested - he still would. Of course I throw in some cash to help maintain his Equipment, probably spend more than would at a LDS in the long run but at least I know what I'm getting.
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