I used to use a fill station in South Florida that offered your choice of air, 32%, 36%, or 40% with tank rentals, with no difference in price; however, I will admit that I generally see pretty high prices for a nitrox fill. For that reason, I will offer the following information about nitrox costs.As far as free Nitrox? Never seen that anywhere.
There is not a lot of use for nitrox in Colorado, where our deepest truly local diving is about 35 feet, so most shops do not offer it. It is only used on out-of-state trips to deeper water. My local dive shop uses nitrox for its instructors on such trips, and they get it from me. So does just about everyone else I know who uses nitrox, especially for decompression gas. I get oxygen from a supplier only when I am about to take one of those far off dive trips, and I don't get any special rate, since I am not a high volume user. I rent the supply cylinders for the time I have them. I have to drive about 35 miles each way to pick up and return the cylinders. I take them with me on the long trips to the deep dive site and mix gas there. I am not looking to make a big profit on this, so I charge enough to cover my costs for cylinder rental, gas, and added travel. I add a little more to cover the cost of the equipment I use for the partial pressure blending.
For what I charge people for the oxygen, a 32% mix comes to about $3.00, plus the air topoff. I would guess that if I had a dedicated fill station and a high volume gas supply, it might cost me about $1.00 per cylinder more to fill it with 32% than to fill it with air.
Keep that in mind the next time someone charges you $20-$25 more for a nitrox fill.