@MARK1992 do the math on the OOA scenario for one diver, and set that as your rock bottom pressure.
100ft-4ata, 1cfm, 3 minute ascent, 5 minute safety stop, 5 minute situation resolution/get back to the anchor. 2*1*3=6cf for ascent, 5*1*1.5~7cf for safety stop. 5*1*4=20cf for the bottom resolution. 6+7+20=33cf=1300psi in an AL80. Obviously substitute whatever variables you are diving in for depth/required distance back to the anchor line or whatever, but that's rough math.
What that says is you need to keep the left tank above 1300psi at all times to be able to get you up to the surface. The goal for "safety" is to maximize the amount of gas you have on you at all times. Left bottle is always "my" bottle, so I prioritize that bottle above all else.
So let's say the boat has some arbitrary be back on the boat with 500psi rule.
The problem with the way I proposed above is on one of the dives, you'll have a 5lb gas differential on the left side. It's totally manageable, we put all stages on the left in backmount, but it's noticeable and some people don't like it. It's the only way to maximize the gas you are going to consume though. Depending on your buddy, you can do your ascent/safety stop on the left bottle to make that delta a bit smaller, but in either instance, one of your bottles is going to have more than the other 2, and you want that bottle to be the left bottle on the last dive.