As far as the relationship between depth and effectiveness of the safety stop, here's an interesting quote from the PADI Encyclopedia, which I find is a good resource in addition to Deco For Divers, since it helps me relate the more general theory to how I was taught to practice rec diving:
"[F]or dives greater than about 30 metres/100 feet, the 5-minute compartment controls. With its short halftime, it eliminates nitrogen rapidly during a safety stop. However, as the depth becomes shallower, control shifts to slower and slower compartments, thereby rendering the 3-minute stop increasingly less effective."
"[F]or dives greater than about 30 metres/100 feet, the 5-minute compartment controls. With its short halftime, it eliminates nitrogen rapidly during a safety stop. However, as the depth becomes shallower, control shifts to slower and slower compartments, thereby rendering the 3-minute stop increasingly less effective."