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From the description though it sounds more like an artificial gill.
http://news.nationalgeographic.com/news/2007/08/070828-scuba-spider.html
http://news.nationalgeographic.com/news/2007/08/070828-scuba-spider.html
Scientists at the University of Bern, Switzerland, determined that spiders use these scuba tanks, called air bells, as reservoirs, monitoring and replenishing oxygen levels to enable the animals to live underwater.
"The water spider's air bell is in some ways working like an external lung," said study co-author Michael Taborsky.
...
As the spider fills the web structure with air, the structure takes on a bell shape and a silvery sheen. The silk membrane allows oxygen to diffuse in from the water and carbon dioxide to diffuse out, so the spiders do not have to replenish the air supply often.