What cert would I need to carry a O2 pony bottle and more importantly Be able to get it filled? I read where some divers breath O2 at the safety stops and they swear by it. And no not just deco divers mentioned this. although deco diving is something I want more info on.
I'm curious as to what purpose you see in it. Is it because you heard divers mention that it makes them feel better? Or is the idea that it might provide extra protection against DCS? If the idea is that it might help you feel better--less tired, for example--then consider experimenting with breathing O2 on the surface. I have heard of people doing that. Lugging along an O2 bottle on a dive for no reason than to use on a safety stop with the idea that it might make you feel better seems like a lot of work to me. Granted, it should be more effective at 20 feet than on the surface, but weighing the annoyance versus the benefit, I know which way I would go. If the idea is to add extra protection against DCS, it seems to me that lugging along an O2 bottle to guard against you taking that one-in-10000-dives "undeserved" hit is likewise not worth it. But maybe you actually like the idea of carrying a bottle. Me, I aim to carry nothing that I don't need.