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Please remember that I am talking about air fills in non-O2 clean tanks.
I equate "reputable" with "responsible". Yes, is there a possibility of an error, but it is a miniscule risk.
I really like these discussions because it shows how people will go to the extreme for scuba diving, but I bet they do not take the same level of safety in their daily lives. I equate analyzing my air fills with wearing a helmet, fire retardant suit, and five-point harness while I drive. Is it safer? Yes. Is it overkill? Yes.
I think it depends on what resources you have available. If you're using a dive shop that only pumps air, then the risks of getting something besides air are essentially nil. If you're using a shop that also pumps nitrox, uses banks, offers trimix, and fills argon bottles, then the risks of getting something besides what you ask for are significantly greater.
The "reputable shop" argument doesn't cut it with me ... a reputable shop would be one that insists that every nitrox diver analyze their tanks when they come in to pick them up. I frequent a reputable shop multiple times a week, and they won't let me out the door with my cylinders until I analyze them ... even the ones I occasionally ask for that only contain air.
Why? ... well ... because the reputable people who fill them are human, and humans sometimes make mistakes. "Trust, but verify" isn't just a political slogan ... for those of us who do a bit more than just occasionally dive a reef or quarry, it's words to live by.
And let's not forget the context of the incident that started this conversation ... that guy was diving inside a cave, carrying multiple breathing gasses. Not analyzing your tanks in that case is blatant complacency ... and at that level of diving, complacency kills.
Only YOU are responsible for your safety ... that extends to verifying that you're breathing what you think you're breathing. In an activity where your ascent profile depends on the gas you use, this seems to me like a no-brainer.
... Bob (Grateful Diver)