I said that high ppo2 ''pulls'' inert gasses out because of the concentration gradient between the blood and the lungs.
But it doesn't. The rate at which N2 comes out of your blood is not related to any other gas. Gases act independent of each other.
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So there are two mechanisms at work. Decompression via pressure gradient and decompression via concentration gradient. M-values refer to pressure gradient, o2 window refferes to concentration gradient.
The oxygen window, to the extent it has anything to do with decompression, refers to the reduced total pressure in your tissues as in less pressure so reduced bubble size but it has nothing to do with oxygen speeding up nitrogen offgassing.
High PP02 deco gasses work simply because you aren't inspiring more n2.