You are on your own. You’re 50 feet deep in one tiny area of the logic I outlined, and paperthin in all the others. You have one mathematical equation that you’re focused on, forgetting all of the other elements that I outlined. In fact, your reasoning is very similar to a paper that starts with: imagine human beings as frictionless spheres.
I already gave you an example where the volume will change — it would actually increase, yet the pressure can be the same, because the exhaust valve is still the same. Therefore, there will be a greater volume of air inside the suit. Again, the pressure is still the same, because it would be created by exactly the same valve setting.
Warmer underwear is thicker. It therefore takes more volume. It also resists the pressure of the outside water. Therefore, it absorbs the pressure of the water, transmitting less of the pressure to the environment around it. Just like a spring. Therefore, it allows a larger volume of air yet still creates the same internal pressure.
remember: the pressure is in pounds per square inch. I still think you are stuck on volume not pressure. Because the thicker underwear has increased the volume, you can have more gas, therefore staying warmer, yet still have the same internal pressure caused by the exact same valve setting.
The other thing is: I can have dramatically different volumes of gas in my suit for exactly the same valve setting. This is not a precise mathematical equation conducted upon frictionless spheres. All of the fine details matter: density of the underwear, volume of the underwear, amount of air added to the suit, the physical position that air occupies, and especially the position and orientation of the exhaust valve.
you’re not asking why the sky is blue. You’re arguing about why one mathematical equation relevant for Raleigh light scattering doesn’t match the exact shade of blue that you’re expecting in the sky, when you’re completely ignoring the presence of things like, say, clouds.
in other words, real life will not distill down to simplistic PV= nRT. There’s a reason that’s called the ideal gas law. Our world is far from ideal: tiny details make a huge differences.
if that’s not enough for you, someone else will have to wade into this. And in the end, none of this will matter one wit to actual diving. The real world experience of millions of dry suit divers shows that the rotation of our exhaust valve is one of the least interesting requirements of how much gas we can keep in and manipulate within our dry suits.
ETA: One more thing I thought to add. Maybe you’re missing this: it’s not just air pressure that determines the volume inside the suit. Why do you think we’re wearing different sizes and thicknesses of underwear? If we only depended upon air pressure alone to determine the volume of air in our suit, we could dive completely naked in our suits and have as much warmth as we wanted, simply by increasing the air pressure (and therefore the volume, and therefore the thickness of the insulating layer). But that doesn’t work for a zillion different reasons, not least of which the air would be so difficult to control due to pressure differentials that it would just never work.
That’s why we wear the underwear in the first place: to resist the external pressure using something other than air pressure — the density of the suit – and to help evenly spread that extra air volume around our entire bodies, even the parts that are experiencing greater external pressure because they might be at a lower depth.