Left side 50% bottle (80cf AL clipped off below primary): regulator hose around back of neck
I never run deco hoses around the neck. I think it's just one step nearer to an avoidable human error. Hoses are 30" and route directly from the cylinder to mouth. I also use ANDI contents tags on the hose (below the reg) as a fail-safe, in addition to cylinder MOD decals and full gas switch protocols.
I don't see any need to 'neck route' a deco cylinder. You don't want the hose there, for any reason, before you reach stop depth. Once at stop depth, the need for simplicity and error reduction outweighs any concept of streamlining.
Wanted to add a 100% mix into the setup, most likely I would get another 80cf AL, anyone would suggest the 40cf AL may be a better option for 100%?
Cylinder volume is dictated by gas requirement.
I have been told by someone to keep all deco bottles on the left? Is this practice mainly for BM people?
This primarily arose from the demands of scootering (in caves). If you're not a DIR/GUE/UTD adept, with an intention to scooter, then it's probably not a big consideration. Bear in mind that GUE doesn't encompass sidemount diving... so that pretty much leaves you with a small number of UTD divers who sidemount. It'd be worth directing that question at them specifically to get their opinion (via the DIR forum).
On balance, far more divers probably rig their cylinders on either side. In doing so, they'd probably follow the 'right-rich/left-lean' philosophy. That's what I do.
If the right side is the correct spot for the 100% mix, what will be the hose routing? I want to avoid using left handed regs / 90 degree swivles etc. Should it go across the chest again like the current primary right bottle?
Yep, right-rich/left-lean. Hoses are stowed on the cylinders during the dive... un-stowed when you need them, breathed, then returned to tank bungees when you move on/up to the next gas. This'll be the same as you were (should have been?) taught on whatever version of advanced nitrox/decompression procedures training you undertook.
Using sidemount configuration doesn't (shouldn't) entail any deviation from full and proper gas switching protocols... or basic considerations for preventing/lessening the risk of killing yourself by accessing the wrong regulator at the wrong depth. IMHO, the necessity to gas switch during the dive on sidemount brings about a
much higher necessity to analyse your kit and ensure that you can never accidentally stick the wrong regulator in your mouth under stress..
Doing a proper 'Tec Sidemount' or re-taking/refreshing tech training
in sidemount, would be the best solution to the questions you are posing. The issues you are raising are ones that will kill you quite easily... that's not really a sound argument for getting online advice from strangers and 'learning from mistakes' by doing the dives without specific and supervised rehearsal.