I just bought some doubles and threw'em on.
You could always do the PADI Tec Basics course?
As KD said, there's nothing special about adding doubles to your kit. However, everything else will change as a result....
You will probably find them more comfortable and balanced than your single. However, the thing you might find different is your wing set up. If you are currently diving a jacket-style BCD, you will want to move to a wing, and one that is sufficiently large for the doubles. I don't know if you dive wet or dry, but if wet, you should consider a double bladder wing, so you have some redundancy on your "floaty bits".
If you are currently diving a wing, and it's big enough, all you need to do is recalculate your buoyancy, rig your regs and away you go. As mentioned, hooking up with someone who is diving doubles now will be helpful in terms of sorting out hose routing. If you Google "DIR hose routing" you'll find lots of information. You should be aware that not all first-stages are equal when it comes to routing. Again, there's several discussions about that topic on here. You will possibly need to get some longer hoses as well.
The only other thing to consider is your reasons for going to doubles. If you aren't diving DIN now, you should allow for that eventuality when you are buying regs and manifolds. It's a much safer system, and as you move towards "the dark side" DIN becomes mandatory.
Just be aware that doubles, like four-wheel drive, allow you get into all sorts of trouble that you might not be able to otherwise. It's pretty hard to mess up too badly on a single 80, but that isn't the case. I own three sets of various sizes, but my bigguns (HP 130s) pretty much allow me to sit at the bottom of a lake for a weekend.
And one final thing, doubles are heavy to schlepp around. You might want to at least look at the side-mount option. My wing is about done, and before I replace it, I'm going to consider that... But then I am old and frail.