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I once worked on a charter boat. A diver surfaced with a headache and wanted O2 so after she emtied the e cylinder of O2 all I had left was some 50%. I offered her that but she declined because she wasn't nitrox ceritified.
There is a big difference between stupid and ignorant. So much for taking advantage of a "teachable moment", huh?...In the Paramedic world we call people like that Oxygen Thieves or TSTL's (too stupid to live)
Last year, after a 200ft cave dive followed by several other dives, I discovered that my O2 bottle had been filled with 60% O2 and 5% Helium. There were no ill effect even though the dive was planned with 100% for deco.