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There are specific circumstances where warm water does freeze before colder water.
I don't really know this, but my guess would be the lower pressure, bringing it closer to it's triple point. My other guess would be it's related to the theta-w.
No, it's hillbilly logic. If the conditions are right for snow, then the air generally has lower humidity, and 'dewpoint'. That's not why it happens, but it seems to be a good corallary.
We're not gonna argue the warm water thing.
Water doesn't freeze at 32* F. Ice melts at 32* F.
Guessing you aren't an air conditioning guy?