Does a tank that is used for nitrox tend to rust more inside requiring more maintenance compared to a tank used exclusively for air?
Never been studied, so all you'll get are people's unsubstantiated personal opinions. Remember that anecdotal evidence ("This is what happened to me....") is the LEAST reliable form of evidence.
There has not been a definitive, controlled study with a large sample size to investigate the question of Nitrox and corrosion.
HOWEVER:
Back in the 1970s the University of Rhode Island did some small studies regarding steel and aluminum scuba cylinder storage. Small, meaning 8 to 10 cylinders, sometimes comparing single matched cylinders.
To make a long story short, one of their conclusions was that, during long-term storage, increased cylinder pressures resulted in increased internal corrosion, which they concluded was from the increased partial pressure of oxygen (pO2). However, there were many other confounding factors such as the composition of the water that caused the rust, the types of valves and snorkel used, (cathode-anode stuff), etc.
My take on the studies is that aluminum cylinders are much less susceptible to corrosion at higher pO2 than steel sylinders.
The studies are controversial because of their methods and small sample sizes.
If you want to read my detailed review of all of these studies, do a search on long-term cylinder storage.