I have never considered intentionally going to about say 600psi on my back tank before switching to the pony (now making it a stage bottle) to extend my dive times.
Personally, I would not do that. All my training so far has been that if I carry a pony it's only for emergencies (unless it's a deco gas). In other words, if I carry a pony, I would only ever use it if I (or someone else) really screwed up (or had some really bizarre accident/malfunction).
That said, if I had some really good reason to do a dive where I felt a need to plan up front to use more gas than my back mount tank, I would probably start the dive on back mount. Then switch to the pony as soon as I got to the bottom. Breathe it down to near empty. Then switch back to my nearly-full back mount tank to complete the dive.
But, really, you should be able to get a handle on things where you can do NDL dives to 100' on a full 100 without having to cut your dive short because you're low on gas (and without needing doubles and without using a pony as part of your dive plan). At least, I *think* so.