Let's figure a worst case scenario.
Let's make the following assumptions:
Interior temperature of the car = 160 degrees Fahrenheit
Tank was filled to 3300 at 70 degrees Fahrenheit (a very good fill!)
What is the pressure in the tank at 160 degrees Fahrenheit?
Using the idea gas law where volume is kept constant:
P2 = P1(T2/T1)
P2 = the pressure at 160 F (619.67 Rankine - the absolute temp we use for gas pressure calculations)
P1 = 3300 (the pressure at 70 F (529.67 Rankine)
T1 = 529.67 R (70 F)
T2 = 619.67 R (160F)
P2 = (3300psi(619.67/529.67))
P2 = 3860.73psi
Worst case, your tank pressure goes up to 3861 psi. Since your tank is probably hydroed to 5000 psi (assuming it's an AL-80), you're OK, provided your burst disk holds up (burst disks for AL-80s are usually rated to 5000 psi).
Ron