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I'd be surprised if you can get anything other than 30-32 on most recreational liveaboards....I think they all use membranes now, so get only one mix out.No reason not to dive Nitrox (EANx) if an appropriate mix (percentage) is available. Keep in mind that while we often think of Nitrox in terms of the more or less standard mixes, like 28%, 32% and 36%, anything between 21% and 40% falls within the definition of ("recreational") Nitrox. There's not a whole lot of difference between air (21%) and EAN28.
For a week of "a lot of diving," I'm not sure I would be too concerned. Even on a liveaboard, 4 dives a day using, say, 32% probably wouldn't be an issue. But maybe I would be more concerned on a 10-day liveaboard. Or if I were using 36% or other relatively rich mix. If I was doing a lot of diving over the course of a 10-day liveaboard or a lot of diving on 36% might I take a break at some point to reduce my oxygen load?--maybe. But by "break" I'm not sure I mean I would dive on air--rather, I think I would just sit out a dive or two.
For further reading, there are a number of threads you can search for where CNS oxygen toxicity, etc., has been discussed in the context of recreational diving. There seems to be some debate as to whether we recreational divers doing a lot of diving over the course of week or so need to be concerned or not.
I'd be surprised if you can get anything other than 30-32 on most recreational liveaboards....I think they all use membranes now, so get only one mix out.
the oxidant: oxygen is bad bad bad..