You should do a full risk assessment and plan the diving comprehensively, to include an emergency plan for any scenarios that could occur.
Things to consider:
1) Surface cover. You need a suitably trained 'spotter' to oversea your diving. They should have adequate communications to the emergency services, along with a comprehensive action plan to respond with. They should have emergency first aid kit, and ideally O2, which they should be trained to use. If currents are a possibility (divers swept away) then you should consider placing your surface cover in a suitable boat.
2) Pre-dive research. It is always worth asking locally if anyone has knowledge of the proposed dive sites. Even non-divers can be a valuable source of information. Fishermen should know the currents, depths etc. Unsupported shore dives make water conditions, especially current, essential. If any current is present, ensure that you recce down-current for several emergency exit points. Your 'worst case' scenario should be strong current, waves and the requirement to tow your injured buddy.
3) Transport. Ensure your transport will reach the site. Avoid lengthy walks from your transport to the site. You, or your buddy, may be exhausted or injured and unable to walk. Assume the worst case...then ask yourself if you can exit the site easily enough. Ensure that emergency medical services can also reach your location - with room to park and turn etc. Ensure that you have written directions to access the site, that you can easily give via telephone. If you are in a very remote location, or if heli evacuation is possible...then ensure you have a realistic idea of where a heli can land or hover.
4) Risk Assessment - Emergency Planning. This should cover any possible injury you could recieve...and aim to reduce/negate the chances of that, along with having a comprehensive plan for how you will deal with it should it occur. Try to google for 'scuba emergency plans' and 'scuba risk assessment' for examples.
5) Hyperbaric Chamber. I've never dived anywhere without knowing exactly where the nearest chamber was...and exactly how long it would take me to get there (the same for any medical treatment). This tends to dictate how aggresively I will dive.
6) Equipment. Have adequate signalling equipment including visual and audible signalling sources. Understand your chances of attracting attention, if you could not extract yourself from the water. Is there boat traffic? From Shore? It is a good idea to have some form of surface support/floatation... either a towed or deployable float.
7) Recording the dives. Take a camera and slate. Make notes and take photos for later trips. Progress your exploration in defined stages, which are the subject of pre-dive planning. Decide a search pattern and navigational plan to ensure that you don't get lost or end the dive at a great distance from your exit point.