2. What kind of stupid question is that?! Like, if I've heard of Nitrox 25%, this will make me more experienced? It does not matter what I've heard (as a matter of fact, I did when I learned this stuff) but if you go on Agressor and sign up for Nitrox they will pump 32 into all Nitrox tanks. Same story in dive shops in most exotic places I go. You choose between air and 32, and be grateful if they even have 32. When I used 36, this was in US, but then again this was the only EAN this dive shop offered me, take it or go on air. So yes, my experience is limited to air, 32 and 36, and I do not see anything wrong with this.
3. In an ideal world I would start calculating the %O2 that will give me max bottom time w/o exceeding the PPO 1.6 (provided this is the only dive of the day) but real world, where I can pick only air or 32, I'll go on air.