My theory on this is that the gas in the dip tube and valve body itself is stagnant enough that it doesnt mix well, and that volume is significant when dropped to ambient pressure.MikeFerrara once bubbled...
A mixture of gases will "mix" but it doesn't always happen immediatly.
...
Finally I dropped it on the flor and rolled it around. Yes, I felt silly. I then analyzed it again and measured 80% almost on the nose. I think adding that small amount of air that slow just didn't mix it up.
The first couple times you were getting poorly mixed gas from the dip tube/valve body and rolling it around and then checking a third time gave you a false coorelation with the rolling.
Note that with a doubles manifold you have even more restricted/dead air space.
As I said, this is just my current guess as to whats happening with these anecdotail gas layering stories I hear.
Roak