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So there isn't a specific technical reason not to bank 40% and top it off with air for leaner mix except your dive profile doesn't need/use 40%?
correct. for what I want, it would require two banks, one of air, one of ean32, or firing up the compressor more regularly. Too much work, not enough benefit.
If helium wasn't so expensive, I'd consider banking ean36 or ean40, but would have to get on trimix sooner. Combine that with the fact that most of the cave and coast shops bank ean32, it makes sense to keep within what has been standardized.