Think the longest I've left a tank (3AL) full and then used it was 6 to 8 months. I personally send out samples of our air for testing and we always hit CGA Grade E. I guess I would draw the line at smell. If it smelled funny, don't use it. I had a guy donate a steel tank that was made in 57, most recent hydro was 2000. I use it as a nice prop in the classroom to show what a J-valve looks like and to reiterate that tanks can last a long time. It has some pressure in it. I have noooo idea how old the air in it is (obviously 2000 or newer). My guess is closer toward that 13 years. It smells like an old, musty museum. I would not use it (lol).